Abstract
Hydrogen consuming microorganisms can cause operational challenges for subterranean hydrogen storage. The systems and methods described herein provide sterilization techniques that include acidifying a subterranean reservoir prior to injection of hydrogen. Acidification may be facilitated by, at least partially, saturating a fluid with an acidifying agent such as carbon dioxide. The subterranean reservoir's fluid may be reduced to 3 pH to 4 pH. Hydrogen may then be injected into the subterranean reservoir for storage.